


Limestones
A limestone is nothing more than just calcium carbonate (CaCO3). It start as floors of shallow tropical seas which is laid down since 150million years ago and is still being formed in parts of the tropics.
When Sea water, which contains carbon dioxide (CO2), escapes warmed by the sun. the calcium and bicarbonate ions in the water combine to form calcium carbonate, just like scale forming in a kettle. This crystallises as calcite.
The famous ooliths (tiny spheres) in limestones are grains of sand or pieces of shell around which calcium carbonate which precipitated from the sea has stuck. The cement that sticks the ooliths together also consists of calcite crystals, which grew either on the sea floor or later in the rock when it was buried.
Shells of sea animals form grains in limestones, and some of them, such as pieces of starfish and sea lilies, promote the growth of cement crystals around themselves particularly well and result in limestones which are especially strong.
Over time, large crystals will grow at the expense of smaller crystals in any limestone, but especially if the stone is buried and warms up. And if it happens to be buried next to where granite is being forced up from deep in the earth near to the edge of a continental plate (when the granite will be at 800-900°C), the limestone will re-crystallise and become marble.